11/13/97


Hello everyone !

We want to change our fixation and processing protocol for pulmonary tissues

and cells to use HEPES buffer instead of sodium cacodylate buffer. Is anybody

out there who has made her/his experience with HEPES buffer in conventional

epoxy resin embedment. We are especially interested in experience of lipid

retention/extraction.



Heinz Fehrenbach (Inst. of Pathology, TU Dresden, Germany)

hefeh@Rcs1.urz.tu-dresden.de


I switched to HEPES about 14 years ago for both my

Paraformaldehyde/Glutaraldehyde buffer and for my osmium buffer. Safer,

better for environment, and cheaper (I think). I noticed no difference

compared to cacodylate (which I had previously used). A couple of years

ago, I got into a discussion in which a colleague was touting PIPES as a

better alternative. The logic is that HEPES has a pKa of 7.5. I use it at

7.4 for my fixes. Aldehyde fixes tend to acidify over time, therefore,

since you start on the low side of the pKa and continue to fight a drop on

that side, you have less buffering capacity. PIPES on the other hand, has

a pKa of 6.8 so if you started at 7.4, you would have more buffering

capacity (0.5 on both sides of the pKa). This is good logic but I didn't

bother switching. Good luck.

Thomas E. Phillips, Ph.D.

Associate Professor of Biological Sciences

Director, Molecular Cytology Core Facility

3 Tucker Hall

University of Missouri

Columbia, MO 65211

(573)-882-4712 (voice)

(573)-882-0123 (fax)

tphillips@biosci.mbp.missouri.edu


We have been experimenting with the use of HEPES as a non-toxic substitute

for NaCacodylate for TEM during the past 6 months. So far the results have

been good for mammalian and amphibian tissues (cardiac muscle, pancreas,

heart, tongue). The membranes look good and we seem to have no trouble

retaining lipid droplets in frog atrial muscle. I would be interested in

anything anyone else has to offer. Also, I am assuming that HEPES is less

toxic than Cacodylate. If anyone knows otherwise, I would like to hear

about it.



Dr. Marie E. Cantino

Dept. of Physiology and Neurobiology, U-131

University of Connecticut

Storrs, CT 06269

Ph: 860-486-3588

Fax: 860-486-1936


[Return to Tips & Tricks Menu]